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Isotopes
Isotopes of the month

Stable Lead Isotopes

Lead in the Environment

Lead, in chemistry also denoted as “Pb” from the Latin “plumbum”, is a commonly found heavy metal. It is not essential for human beings. In contrast, it has toxic effects on human health, once it is ingested via contaminated water or food, or inhaled as dust. The international agency for re-search on cancer, IARC, classified lead as being potentially/ probably carcinogenic. Especially chil-dren are affected by an exposure to lead: It can cause harm to their nervous systems. For adults, lead has harmful effects on the oxygen supply of the cells.
Lead is emitted by mining and smelting industries as well as by the combustion of coal. Although leaded gasoline (anti-knock agent) was banned, a main source of lead emissions in Germany is still road transport, because of the abrasion of tires and brakes. After a deposition on the soil, the lead is further distributed in the environment as it leaches out of the soils into rivers, lakes and into the groundwater. Furthermore, the use of lead e.g. in batteries or ammunition is a source of lead found in the environment.


Lead-Isotopes

The four most important lead isotopes occurring in the environment are 204Pb, 206Pb, 207Pb and 208Pb. They are stable, which means they are not radioactive and do not decay. 204Pb is a so-called primordial nuclide. The term primordial denotes an isotope, which was already present when the earth was formed. The three isotopes 206Pb, 207Pb and 208Pb are, in contrast, final products of the decay chains of the radioactive isotopes 238Uran, 235Uran and 232Thorium.
The frequency of occurrence of the three Pb-isotopes, therefore, depends on the original concen-trations of lead, uranium and thorium, as well as on the half-life of their parent nuclides.

Stable isotopes are measured as ratio of two isotopes of one element. The values of lead isotopes are, for example, given as the ratio 206Pb/207Pb or 208Pb/206Pb. The Pb-isotope ratios vary for dif-ferent lead deposits, because the half-lives of the parent isotopes are different. The specific Pb-isotope ratio of each deposit, hence, depends on the geological age, at which the parent isotopes became present in the deposits, and on the amount of parent isotopes before the decay started.
In contrast to other stable isotopes like 18O or 2H, Pb-isotope ratios do not show a significant frac-tionation. Isotope ratios, which differ from the natural ratios of the lead deposits are a result of mixed lead from several deposits.
Pb-isotope ratios are mainly measured using a mass spectrometry with thermal ionization (TIMS) or with inductively coupled plasma, e.g. with quadrupole (ICP-QMS).
Beside the stable lead isotopes, many other short-lived Pb-isotopes exist, like 210Pb, which are determined using alpha-spectrometry or liquid scintillation counting (LSC).


Application of Stable Lead-isotopes

Measuring stable Pb-isotopes can be helpful to identify the source of lead, which was found in e.g. groundwater or soils. With the measurements, it can be clarified, whether the lead occurs naturally in this region or is of anthropogenic origin. It is not sufficient to measure the concentration in order to determine the origin of lead.
The determination of the origin of lead is possible, because each lead deposit has its specific Pb-isotope ratio value. Lead in processed materials deviates from this deposit specific isotope ratio, as the processed lead was transported over long distances or was mixed with lead from other depos-its. Lead, which has an anthropogenic influence, can therefore be distinguished from local, geo-genic occurring lead. The differences are visible when the isotope ratios are shown in a diagram. This is applied for some examples in figure 1.
Samples for the analysis of Pb-isotope ratios are taken in groundwaters, or so called geo/- or cli-mate archives, such as lake sediments, swamp, tree rings or undisturbed soil, whose layers can be dated back. In forensic science, lead isotope ratios are used as well. Lead accumulates in bones and teethes over the lifetime. Because of that, it can be determined where a person had lived at a certain time of his life.

Komarek et al.2007Figure 1: Isotope ratios of some sources of lead (Komarek et al., 2007).


Study case: Where does the lead come from?

A group of scientists from northern Europe performed a Pb-isotope analysis on samples from western Greenland (Bindler et al., 2001). They found, that inspite western Greenland has a shorter distance to North America than to Eurasia, the Pb-isotope ratio shows the signature of Eurasian lead. Russian emissions seem to be responsible for most of the emissions in the northern part, whereas for the southern part of Greenland, Europe is the major emitter of the lead found.
At Lake Constance, Pb-isotope analysis was conducted as well (Kober et al., 1999). It was possible to distinguish natural, geogenic from anthropogenic lead using 208Pb/206Pb and 207Pb/206Pb isotope ratios. Because of the differences of anthropogenic and natural lead in the isotope ratios, the an-thropogenic input could be investigated. The results of the scientist from Heidelberg and Konstanz are shown in figure 2.
The increasing values of the 208Pb/206Pb ratio from the mid-19th century show, according to Kober et al. (1999), the rising input of anthropogenic lead in the course of the industrialization.
Main sources of the in Lake Constance deposited atmospheric lead, were the combustion of coal, iron ore processing and the use of leaded gasoline. The highest depositions were measured for the 1970s and 1980s.
After the 208Pb/206Pb peak at about 1980, the ratio is decreasing again, with an extreme event in 1987. This decrease of anthropogenic input, can be explained by the ban of leaded gasoline and environmental precautions. The very low 208Pb/206Pb ratio in the year 1987 was attributed to a flood event in this year. Because of the flood, mobilized geogenic lead mixed with the anthropo-genic lead and, hence, weakened the signal of the anthropogenic lead.

Kober et al. 1999Figure 2: Time course of the 208Pb/206Pb isotope ratio
measured at sediment cores of Lake Constance (Kober et al., 1999).


Application in Hydrogeology

In case elevated lead concentrations are measured in groundwater, analysis of lead isotope ratios can be necessary. Like described above, the analysis can reveal whether the lead has an anthropo-genic source or occurs naturally. A typical source of anthropogenic lead in groundwater is, for ex-ample, ammunition or leaded gasoline.

 

Literature

Bindler, R., Renberg, I., Anderson, N. J., Appleby, P. G., Emteryd, O., & Boyle, J. (2001). Pb isotope ratios of lake sediments in West Greenland: inferences on pollution sources. Atmospheric Environment, 35(27), 4675-4685.


Komárek, M., Ettler, V., Chrastný, V., & Mihaljevič, M. (2008). Lead isotopes in environmental sciences: a review. Environment international, 34(4), 562-577.


Kober, B., Wessels, M., Bollhöfer, A., & Mangini, A. (1999). Pb isotopes in sediments of Lake Constance, Central Europe constrain the heavy metal pathways and the pollution history of the catchment, the lake and the region-al atmosphere. Geochimica et Cosmochimica Acta, 63(9), 1293-1303.

 

Isotopes of the Month as download

lead isotopes (November 2018) Pb-206/-207/-208

technetium-99 (m) (April 2016) Tc-99

uranium (September 2015) U-234/-235/-238

chlorine-37/-35 (March 2015) Cl-37

strontium-87/-86 (February 2015) Sr-87

sulphur-34 (June 2014) S-34

carbon-13 (August 2013) C-13

krypton-85 (May 2013) Kr-85

tritium (April 2013) H-3

oxygen-18 (March 2013) O-18